Comment on “The ligand polyhedral model approach to the mechanism of complete carbonyl exchange in [Rh4(CO)12] and [Rh6(CO)16]” by Brian F. G. Johnson, Dalton Transactions, 2015, 44, DOI: 10.1039/C4DT03360D-Reference-Cited by-同舟云学术

Comment on “The ligand polyhedral model approach to the mechanism of complete carbonyl exchange in [Rh4(CO)12] and [Rh6(CO)16]” by Brian F. G. Johnson, Dalton Transactions, 2015, 44, DOI: 10.1039/C4DT03360D

Published:2015 Issue:37 Volume:44 Page:16611-16613
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Heaton Brian T.¹²³⁴,Grachova Elena V.⁵⁶⁷⁸,Tunik Sergey P.⁵⁶⁷⁸,Podkorytov Ivan S.⁹⁶⁷⁸

Affiliation:

1. Chemical Laboratory

2. University of Liverpool

3. Liverpool L69 7ZD

4. UK

5. Department of Chemistry

6. St. Petersburg State University

7. St. Petersburg 198504

8. Russia

9. Biomolecular NMR Laboratory

Abstract

Use of the LPM to provide a general mechanism for ligand fluxionality in Rh-containing carbonyl clusters in solution is questioned.

Funder

Russian Foundation for Basic Research

Saint Petersburg State University

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT01099C

Reference29 articles.

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2. The structures of simple binary carbonyls

3. Structures of binary carbonyls and related compounds. Part 1. A new approach to fluxional behaviour

4. Mechanism of the low-energy fluxional process in [Fe3(CO)12 − nL n] [n = 0–2(3)]: a rebuttal

5. Mechanism of the low-energy fluxional process in [Fe3(CO)12−nL n] (n = 0–2): a perspective

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