Frustrated Lewis pair catalyzed hydrodehalogenation of benzyl-halides-Reference-Cited by-同舟云学术

Frustrated Lewis pair catalyzed hydrodehalogenation of benzyl-halides

Published:2022 Issue:8 Volume:58 Page:1175-1178
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Wang Tongtong¹²,Xu Maotong¹,Jupp Andrew R.¹,Chen Shi-Ming¹^ORCID,Qu Zheng-Wang³^ORCID,Grimme Stefan³^ORCID,Stephan Douglas W.¹^ORCID

Affiliation:

1. Department of Chemistry, University of Toronto, 80 St. George St, Toronto, ON, M5S3H6, Canada

2. College of Chemistry, Faculty of Chemical, Environmental and Biological Science and Technology, Dalian University of Technology, Dalian 116023, China

3. Mulliken Center for Theoretical Chemistry, University of Bonn, Beringstrasse 4, Bonn 53115, Germany

Abstract

The FLP B(2,6-C6F2H3)3/tetramethylpiperidine (TMP) in the presence of H2 (or D2) catalyzes the hydrodehalogenation of benzyl-halides affording the corresponding toluene derivatives.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D1CC05943B

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