Evidence for a kinetic FLP reaction pathway in the activation of benzyl chlorides by alkali metal–phosphine pairs-Reference-Cited by-同舟云学术

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Evidence for a kinetic FLP reaction pathway in the activation of benzyl chlorides by alkali metal–phosphine pairs

Published:2024 Issue:35 Volume:53 Page:14582-14586
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Csókás Dániel¹,Coles Max²^ORCID,Toh Zhi Hao³,Young Rowan D.²^ORCID

Affiliation:

1. Institute of Organic Chemistry, HUN-REN Research Centre for Natural Sciences, H-1117 Budapest, Hungary

2. School of Chemistry and Molecular Biosciences, University of Queensland, 68 Cooper Road, Australia 4067

3. Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore 117543

Abstract

The presence of Na+ is found to accelerate Bn−Cl bond cleavage by PPh3via a kinetic frustrated Lewis pair (FLP) pathway.

Funder

Nemzeti Kutatási Fejlesztési és Innovációs Hivatal

Australian Research Council

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT02028F

Reference48 articles.

1. Frustrated Lewis Pairs

2. Frustrated Lewis Pairs: Discovery and Overviews in Catalysis

3. Diverse Uses of the Reaction of Frustrated Lewis Pair (FLP) with Hydrogen

4. J. C.Slootweg and A. R.Jupp , Frustrated Lewis Pairs , Springer , Cham , 2021

5. New Directions for Frustrated Lewis Pair Chemistry

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