Polymorphism and optical, magnetic and thermal properties of the either phyllo- or inosilicate-analogous borosulfate Cu[B2(SO4)4]-Reference-Cited by-同舟云学术

Polymorphism and optical, magnetic and thermal properties of the either phyllo- or inosilicate-analogous borosulfate Cu[B₂(SO₄)₄]

Published:2022 Issue:8 Volume:51 Page:3104-3115
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Hämmer Matthias¹^ORCID,Pielnhofer Florian²^ORCID,Janka Oliver³⁴^ORCID,Takahashi Hirotaka¹,Gross Peter¹,Pöttgen Rainer⁴^ORCID,Höppe Henning A.¹^ORCID

Affiliation:

1. Institut für Physik, Universität Augsburg, Universitätsstraße 1, 86159 Augsburg, Germany

2. Institut für Anorganische Chemie, Universität Regensburg, Universitätstraße 31, 93053 Regensburg, Germany

3. Universität des Saarlandes, Anorganische Festkörperchemie, Campus C4 1, 66123 Saarbrücken, Germany

4. Institut für Anorganische und Analytische Chemie, Westfälische Wilhelms-Universität Münster, Corrensstraße 30, 48149 Münster, Germany

Abstract

Reaction of Cu2[(OH)2CO3], H3BO3 and oleum yields either inosilicate-analogous α-Cu[B2(SO4)4] or the new phyllosilicate-analogous β-Cu[B2(SO4)4], both subject to Jahn–Teller distortion; two polymorphs of Cu(HSO4)2 and Cu[S2O7] are also reported.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D1DT04090A

Reference64 articles.

1. Sn[B2 O3 F2 ]-The First Tin Fluorooxoborate as Possible NLO Material

2. The very first normal-pressure tin borate Sn3B4O9, and the intermediate Sn2[B7O12]F

3. On the phosphors Na5M(WO4)4 (M = Y, La–Nd, Sm–Lu, Bi) – crystal structures, thermal decomposition, and optical and magnetic properties

4. Tb(HSO4)(SO4) – a green emitting hydrogensulfate sulfate with second harmonic generation response

5. RE2[B2(SO4)6] (RE = Y, La–Nd, Sm, Eu, Tb–Lu): a silicate-analogous host structure with weak coordination behaviour

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