Cd[B2(SO4)4] and H2[B2(SO4)4] – a phyllosilicate-analogous borosulfate and its homeotypic heteropolyacid-Reference-Cited by-同舟云学术

Cd[B₂(SO₄)₄] and H₂[B₂(SO₄)₄] – a phyllosilicate-analogous borosulfate and its homeotypic heteropolyacid

Published:2022 Issue:40 Volume:51 Page:15458-15466
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Hämmer Matthias¹^ORCID,Pasqualini Leonard C.²^ORCID,Sebastian Sean S.³^ORCID,Huppertz Hubert²^ORCID,Höppe Henning A.¹^ORCID,Bruns Jörn³^ORCID

Affiliation:

1. Institute of Physics, University Augsburg, Universitätsstraße 1, 86159 Augsburg, Germany

2. Institute of General, Inorganic and Theoretical Chemistry, University of Innsbruck, Innrain 80-82, 6020 Innsbruck, Austria

3. Institute of Inorganic Chemistry, University of Cologne, Greinstraße 6, 50939 Cologne, Germany

Abstract

The phyllosilicate-analoguous borosulfate H2[B2(SO4)4] and its cadmium salt, Cd[B2(SO4)4], have been synthesized via various paths and analyzed thoroughly. The heteropolyacid is the second structurally determined acid within borosulfate chemistry.

Funder

Fonds der Chemischen Industrie

Universität Innsbruck

Deutsche Forschungsgemeinschaft

Max-Buchner-Forschungsstiftung

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT02344J

Reference56 articles.

1. Borosulfates—Synthesis and Structural Chemistry of Silicate Analogue Compounds

2. The First Bismuth Borosulfates Comprising Oxonium and a Tectosilicate‐Analogous Anion

3. A Deep‐UV Nonlinear Optical Borosulfate with Incommensurate Modulations

4. Strong Lewis and Brønsted Acidic Sites in the Borosulfate Mg 3 [H 2 O→B(SO 4 ) 3 ] 2

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