Selecting the spin crossover profile with controlled crystallization of mononuclear Fe(iii) polymorphs

Author:

Vicente Ana I.12345ORCID,Ferreira Liliana P.62345ORCID,Carvalho Maria de Deus12345,Rodrigues Vítor H. N.7895,Dîrtu Marinela M.1011121314ORCID,Garcia Yann1011121314ORCID,Calhorda Maria José12345ORCID,Martinho Paulo N.12345ORCID

Affiliation:

1. Centro de Química e Bioquímica

2. Faculdade de Ciências

3. Universidade de Lisboa

4. 1749-016 Lisboa

5. Portugal

6. Biosystems and Integrative Sciences Institute (BioISI)

7. Physics Department

8. University of Coimbra

9. 3004-516 Coimbra

10. Institute of Condensed Matter and Nanosciences

11. Molecules

12. Solids and Reactivity (IMCN/MOST)

13. Université Catholique de Louvain

14. 1348 Louvain-la-Neuve

Abstract

Two polymorphic species of the [Fe(5-Br-salEen)2]ClO4 compound were obtained, each of them being selectively recovered after evaporation of the solvent at a controlled rate.

Funder

Fundação para a Ciência e a Tecnologia

Fonds De La Recherche Scientifique - FNRS

European Cooperation in Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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