The strong correlations between thermal conductivities and electronic spin states in the crystals of Fe(iii) spin crossover complexes

Author:

Hoshino Norihisa1ORCID,Hayashi Akari2,Akutagawa Tomoyuki23ORCID

Affiliation:

1. Department of Materials Science and Technology, Faculty of Engineering, Niigata University, 8050 Ikarashi-2, Niigata 950-2181, Japan

2. Graduate School of Engineering, Tohoku University, 6-6 Aza-aoba, Aramaki, Aoba-ku, Sendai 980-8579, Japan

3. Institute of Multidisciplinary Research for Advanced Materials (IMRAM), Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577, Japan

Abstract

The temperature dependence of the thermal conductivities of the Fe(iii) complexes was greatly affected by the spin state transitions. This indicates that SCO complexes are promising candidates for heat transportation switch materials.

Funder

Ministry of Education, Culture, Sports, Science and Technology

Sumitomo Foundation

Core Research for Evolutional Science and Technology

Shorai Foundation for Science and Technology

Iketani Science and Technology Foundation

Tokuyama Science Foundation

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference38 articles.

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2. V. A.Konstantinov , in Heat Transfer – Theoretical Analysis, Experimental Investigations and Industrial Systems , ed. A. Belmiloudi , InTech , 2011

3. Anomalously low electronic thermal conductivity in metallic vanadium dioxide

4. Photomechanical Response of Diarylethene Single Crystals , ed. M. Irie , Y. Yokoyama and T. Seki , Springer , Tokyo, Japan , 2013

5. Thermal conductivity of bis-tetramethyltetraselenafulvalene perchlorate [(TMTSF)2ClO4]

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