Anomalously low electronic thermal conductivity in metallic vanadium dioxide

Author:

Lee Sangwook12,Hippalgaonkar Kedar34,Yang Fan35,Hong Jiawang67,Ko Changhyun1,Suh Joonki1,Liu Kai18,Wang Kevin1,Urban Jeffrey J.5,Zhang Xiang389,Dames Chris38,Hartnoll Sean A.10,Delaire Olivier711,Wu Junqiao18

Affiliation:

1. Department of Materials Science and Engineering, University of California, Berkeley, CA 94720, USA.

2. School of Materials Science and Engineering, Kyungpook National University, Daegu 41566, South Korea.

3. Department of Mechanical Engineering, University of California, Berkeley, CA 94720, USA.

4. Institute of Materials Research and Engineering, A*STAR (Agency for Science, Technology and Research), 2 Fusionopolis Way, Innovis, 08-03, 138634 Singapore.

5. The Molecular Foundry, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA.

6. School of Aerospace Engineering and Institute of Advanced Structure Technology, Beijing Institute of Technology, Beijing 100081, China.

7. Materials Science and Technology Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA.

8. Materials Sciences Division, LBNL, Berkeley, CA 94720, USA.

9. Department of Physics, King Abdulaziz University, Jeddah 21589, Saudi Arabia.

10. Department of Physics, Stanford University, Stanford, CA 94305, USA.

11. Department of Mechanical Engineering and Materials Science, Duke University, Durham, NC 27708, USA.

Abstract

Decoupling charge and heat transport In metals, electrons carry both charge and heat. As a consequence, electrical conductivity and the electronic contribution to the thermal conductivity are typically proportional to each other. Lee et al. found a large violation of this so-called Wiedemann-Franz law near the insulator-metal transition in VO 2 nanobeams. In the metallic phase, the electronic contribution to thermal conductivity was much smaller than what would be expected from the Wiedemann-Franz law. The results can be explained in terms of independent propagation of charge and heat in a strongly correlated system. Science , this issue p. 371

Funder

A*STAR of Singapore

Science and Engineering Research Council

National Science Foundation of China

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

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