Vibrational characterization of a diiron bridging hydride complex – a model for hydrogen catalysis

Author:

Gee Leland B.1234ORCID,Pelmenschikov Vladimir5678ORCID,Wang Hongxin9104ORCID,Mishra Nakul111124ORCID,Liu Yu-Chiao1314151617ORCID,Yoda Yoshitaka181920,Tamasaku Kenji2120,Chiang Ming-Hsi1314151617ORCID,Cramer Stephen P.9104ORCID

Affiliation:

1. Department of Chemistry

2. Stanford University

3. Stanford

4. USA

5. Institut für Chemie

6. Technische Universität Berlin

7. 10623 Berlin

8. Germany

9. SETI Institute

10. Mountain View

11. University of California, Davis

12. Davis

13. Institute of Chemistry

14. Academia Sinica

15. Taipei 115

16. Taiwan

17. Department of Medicinal and Applied Chemistry

18. Japan Synchrotron Radiation Research Institute (JASRI)

19. SPring-8

20. Japan

21. RIKEN SPring-8 Center

Abstract

Fe–H–Fe bridging iron hydrides in model systems and metalloenzymes: benefits and challenges in revealing their vibrational signatures using NRVS spectroscopy and DFT calculations.

Funder

Deutsche Forschungsgemeinschaft

National Institute of General Medical Sciences

National Science Foundation

Einstein Stiftung Berlin

Ministry of Science and Technology, Taiwan

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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