Substrate-Gated Transformation of a Pre-Catalyst into an Iron-Hydride Intermediate [(NO)2(CO)Fe(μ-H)Fe(CO)(NO)2] for Catalytic Dehydrogenation of Dimethylamine Borane

Author:

Tseng Yu-Ting12ORCID,Pelmenschikov Vladimir3ORCID,Iffland-Mühlhaus Linda4,Calabrese Donato5,Chang Yu-Che2,Laun Konstantin3,Pao Chih-Wen6,Sergueev Ilya7,Yoda Yoshitaka8,Liaw Wen-Feng1ORCID,Chen Chien-Hong9ORCID,Hsu I-Jui10ORCID,Apfel Ulf-Peter411ORCID,Caserta Giorgio3ORCID,Lauterbach Lars5,Lu Tsai-Te12ORCID

Affiliation:

1. Department of Chemistry, National Tsing Hua University, Hsinchu 30013, Taiwan

2. Institute of Biomedical Engineering, National Tsing Hua University, Hsinchu 30013, Taiwan

3. Institut für Chemie, Technische Universität Berlin, Berlin 10623, Germany

4. Department of Chemistry and Biochemistry, Inorganic Chemistry Ι, Ruhr-Universität Bochum, Bochum 44801, Germany

5. Institute of Applied Microbiology, RWTH Aachen University, Aachen 52074, Germany

6. National Synchrotron Radiation Research Center, Hsinchu 30076, Taiwan

7. Deutsches Elektronen-Synchrotron DESY, Hamburg D-22607, Germany

8. JASRI, SPring-8, Sayo-gun, Hyogo 679-5198, Japan

9. Department of Medical Applied Chemistry, Chung Shan Medical University and Department of Medical Education, Chung Shan Medical University Hospital, Taichung 40201, Taiwan

10. Department of Molecular Science and Engineering, Research and Development Center of Smart Textile Technology, National Taipei University of Technology, Taipei 10608, Taiwan

11. Department for Electrosynthesis, Fraunhofer UMSICHT, Oberhausen 46047, Germany

Funder

Deutsche Forschungsgemeinschaft

Fraunhofer-Gesellschaft

Ministry of Science and Technology, Taiwan

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

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