NHC catalyzed enantioselective Coates-Claisen rearrangement: a rapid access to the dihydropyran core for oleuropein based secoiridoids
Author:
Affiliation:
1. Department of Chemistry
2. National Institute of Technology
3. Tiruchirappalli-620015
4. India
5. Division of Chemistry and Biological Chemistry
6. School of Physical & Mathematical Sciences
7. Nanyang Technological University
8. Singapore
Abstract
A simple protocol for the synthesis of the dihydropyran core structure of secoiridoids using NHC catalyzed Coates-Claisen rearrangement is described.
Funder
Department of Science and Technology, Ministry of Science and Technology
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,General Chemistry,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2018/NJ/C7NJ04057A
Reference65 articles.
1. Highlights in Oleuropein Aglycone structure
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3. Naturally Occurring Iridoids. A Review, Part 1
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5. Iridoids. An Updated Review, Part II
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