Acoustic phonons and negative thermal expansion in MOF-5-Reference-Cited by-同舟云学术

Acoustic phonons and negative thermal expansion in MOF-5

Published:2014 Issue:39 Volume:16 Page:21144-21152
ISSN:1463-9076
Container-title:Phys. Chem. Chem. Phys.
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Rimmer Leila H. N.¹²³,Dove Martin T.¹²³⁴⁵,Goodwin Andrew L.⁶⁷⁸⁹,Palmer David C.¹⁰¹¹¹²¹³

Affiliation:

1. Department of Earth Sciences

2. University of Cambridge

3. Cambridge CB2 3EQ, UK

4. School of Physics & Astronomy and Materials Research Institute

5. Queen Mary University of London

6. Inorganic Chemistry Laboratory

7. Department of Chemistry

8. University of Oxford

9. Oxford, UK

10. CrystalMaker Software Limited

11. Centre for Innovation & Enterprise

12. Oxford University Begbroke Science Park

13. Begbroke, UK

Abstract

An acoustic phonon with a mechanism not previously documented (motion of rigid benzene dicarboxylate ligands and ZnO₄ tetrahedra) makes a sizeable contribution to the overall NTE in MOF-5.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2014/CP/C4CP01701C

Reference31 articles.

1. Two Decades of Negative Thermal Expansion Research: Where Do We Stand?

2. C. P. Romao , K. J.Miller , C. A.Whitman , M. A.White and B. A.Marinkovic , in Comprehensive Inorganic Chemistry II , ed. J. Reedijk and K. Poeppelmeier , Elsevier , Amsterdam , 2nd edn, 2013 , ch. 4.07 – Negative Thermal Expansion (Thermomiotic) Materials, pp. 127–151

3. Negative thermal expansion in beta-quartz

4. Geometrical Origin and Theory of Negative Thermal Expansion in Framework Structures

5. Negative thermal expansion and low-frequency modes in cyanide-bridged framework materials

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