All-round robustness of the Mn19 coordination cluster system: experimental validation of a theoretical prediction-Reference-Cited by-同舟云学术

All-round robustness of the Mn19 coordination cluster system: experimental validation of a theoretical prediction

Published:2014 Issue:44 Volume:50 Page:5847-5850
ISSN:1359-7345
Container-title:Chem. Commun.
language:en
Short-container-title:Chem. Commun.

Author:

Ako Ayuk M.¹²³⁴²,Lan Yanhua¹²³,Hampe Oliver⁴²⁵,Cremades Eduard⁶⁷⁸,Ruiz Eliseo⁶⁷⁸,Anson Christopher E.¹²³,Powell Annie K.¹²³⁴²

Affiliation:

1. Institut für Anorganische Chemie

2. Karlsruhe Institute of Technology

3. Karlsruhe, Germany

4. Institut für Nanotechnologie

5. D-76344 Eggenstein-Leopoldshafen, Germany

6. Departament de Química Inorgànica and Institut de Recerca de Química Teòrica i Computacional

7. Universitat de Barcelona

8. 08028 Barcelona, Spain

Abstract

Experimental and theoretical studies confirm that the maximum possible ground spin state of S_T = 83/2 for the Mn₁₉ aggregate is insensitive to replacement of its eight μ₃-N₃ ligands by μ₃-Cl, μ₃-Br, μ₃-OH or μ₃-OMe.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2014/CC/C4CC01264J

Reference21 articles.

1. Magnetic memory of a single-molecule quantum magnet wired to a gold surface

2. Single-Molecule-Magnet Carbon-Nanotube Hybrids

3. A Ferromagnetically Coupled Mn19 Aggregate with a RecordS=83/2 Ground Spin State

4. Defective Double-Cubane, Tetranuclear Manganese(II) and Cobalt(II) Complexes with Simultaneous μ1,1-Azido and μ-O Bridges

5. Reactivity in polynuclear transition metal chemistry as a means to obtain high-spin molecules: substitution of µ4-OH– by η1,µ4-N3– increases nine times the ground-state S value of a nonanuclear nickel(ii) cage

Cited by 17 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. A spherical capped square antiprismatic DyIII complex encapsulated three acylhydrazone Schiff base ligands behaving field-induced single-ion magnet behaviour;Journal of Molecular Structure;2023-08

2. Influence of Mn/Ca ratio in Mn-Ca coordination clusters: Synthesis, structure, and magnetic characterisation;Polyhedron;2021-09

3. Hexanuclear NiII4LnIII2 Complexes with SMM Behavior at Zero Field for Ln = Tb, Dy, Ho;Crystal Growth & Design;2020-09-28

4. Bioinspired Water Oxidation Using a Mn-Oxo Cluster Stabilized by Non-Innocent Organic Tyrosine Y161 and Plastoquinone Mimics;ACS Sustainable Chemistry & Engineering;2020-08-17

5. Synthesis of new Mn19 analogues and their structural, electrochemical and catalytic properties;Dalton Transactions;2019