Synthesis of new Mn19 analogues and their structural, electrochemical and catalytic properties-Reference-Cited by-同舟云学术

Synthesis of new Mn19 analogues and their structural, electrochemical and catalytic properties

Published:2019 Issue:15 Volume:48 Page:4830-4836
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Chevallot-Beroux Elodie¹²³⁴,Ako Ayuk M.⁵⁶⁷⁸,Schmitt Wolfgang⁵⁶⁷⁸^ORCID,Twamley Brendan⁵⁶⁷⁸,Moran Joseph¹²³⁴^ORCID,Corinne Boudon⁹¹⁰¹¹¹²¹³,Ruhlmann Laurent⁹¹⁰¹¹¹²¹³,Mameri Samir¹⁴¹⁵¹⁶⁴^ORCID

Affiliation:

1. Laboratory of Chemical Catalysis

2. University of Strasbourg

3. Strasbourg 67083

4. France

5. School of Chemistry & CRANN

6. University of Dublin

7. Dublin 2

8. Ireland

9. Laboratoire d'Electrochimie et de Chimie Physique du Corps Solide

10. Institut de Chimie

11. UMR CNRS 7177

12. Université de Strasbourg

13. Strasbourg 67081

14. IUT Robert Schuman

15. Département Chimie

16. Illkirch 67411

Abstract

We report the synthesis, structural characterisation, electrochemistry and catalytic activity in the selective oxidation of benzyl alcohol of new Mn₁₉ and Mn₁₈M analogues: [MnIII12MnII7(μ₄-O)₈(μ₃-OCH₃)₂(μ₃-Br)₆(HL^Me)₁₂(MeOH)₆]Br₂ (2) and [MnIII12MnII6Sr(μ₄-O₈(μ₃-Cl)₈(HL^Me)₁₂(MeCN)₆]Cl₂ cluster (3), where H₃L^Me is 2,6-bis(hydroxymethyl)-p-cresol.