Infrared characterization of the products and the rate coefficient of the reaction between Criegee intermediate CH2OO and HCl-Reference-Cited by-同舟云学术

Infrared characterization of the products and the rate coefficient of the reaction between Criegee intermediate CH2OO and HCl

Published:2021 Issue:18 Volume:23 Page:11082-11090
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Liang Wei-Che¹²³⁴,Luo Pei-Ling¹²³⁴⁵^ORCID,Lee Yuan-Pern¹²³⁴⁵^ORCID

Affiliation:

1. Department of Applied Chemistry and Institute of Molecular Science

2. National Yang Ming Chiao Tung University

3. Hsinchu 300093

4. Taiwan

5. Institute of Atomic and Molecular Sciences

Abstract

Infrared spectrum of chloromethyl hydroperoxide, the reaction product of Criegee intermediate CH₂OO with HCl, was obtained. Secondary products CHClO and H₂O were also observed. The rate coefficient was determined to be 4.8 × 10⁻¹¹ cm³ molecule⁻¹ s⁻¹.

Funder

Ministry of Science and Technology, Taiwan

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CP/D1CP00011J

Reference36 articles.

1. Gas-Phase Ozonolysis of Alkenes. Recent Advances in Mechanistic Investigations

2. The gas-phase ozonolysis of unsaturated volatile organic compounds in the troposphere

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