Alkyl groups as electron density donors in π-hole bonding
Author:
Affiliation:
1. Departament de Química Inorgànica i Orgànica and Institut de Química Teòrica i Computacional (IQTC-UB)
2. Universitat de Barcelona
3. 08028 Barcelona
4. Spain
Abstract
A combined structural and computational analysis has demonstrated that alkyl groups can act as Lewis bases in π-hole bonding.
Funder
Ministerio de Economía y Competitividad
Publisher
Royal Society of Chemistry (RSC)
Subject
Condensed Matter Physics,General Materials Science,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/CE/C7CE01259D
Reference50 articles.
1. Noncovalent Interactions: A Challenge for Experiment and Theory
2. Unorthodox Interactions at Work
3. σ-Holes, π-holes and electrostatically-driven interactions
4. σ-Hole Bond vs π-Hole Bond: A Comparison Based on Halogen Bond
5. Use of the electrostatic potential at the molecular surface to interpret and predict nucleophilic processes
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