Role of the metal cation types around VO4 groups on the nonlinear optical behavior of materials: experimental and theoretical analysis

Author:

Su Xin12345,Yang Zhihua1234,Han Guopeng12345,Wang Ying1234,Wen Ming12345,Pan Shilie1234

Affiliation:

1. Key Laboratory of Functional Materials and Devices for Special Environments of CAS; Xinjiang Key Laboratory of Electronic Information Materials and Devices

2. Xinjiang Technical Institute of Physics & Chemistry of CAS

3. Urumqi 830011

4. China

5. University of Chinese Academy of Sciences

Abstract

We combined experimental and theoretical studies of βII-Li3VO4, KCd4(VO4)3 and Ca3(VO4)2 crystals, which turns out that the metal cation types and coordination around VO4 groups, the distorted and parallel oriented VO4 tetrahedron, could produce the large SHG coefficient.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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