K3V2O3F4(IO3)3: a high-performance SHG crystal containing both five and six-coordinated V5+ cations-Reference-Cited by-同舟云学术

K3V2O3F4(IO3)3: a high-performance SHG crystal containing both five and six-coordinated V5+ cations

Published:2022 Issue:2 Volume:13 Page:454-460
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Chen Jin¹²³^ORCID,Hu Chun-Li¹,Lin Yi-Lin¹^ORCID,Chen Yan¹^ORCID,Chen Qian-Qian¹,Mao Jiang-Gao¹^ORCID

Affiliation:

1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, P. R. China

2. College of Chemistry and Materials Science, Fujian Provincial Key Laboratory of Polymer Materials, Fujian Normal University, Fuzhou, 350007, P. R. China

3. University of Chinese Academy of Sciences, Beijing 100039, P. R. China

Abstract

K3V2O3F4(IO3)3, which is the first metal vanadium iodate containing two different V-centered polyhedra, exhibits a strong SHG effect of 1.3 × KTP and a large birefringence of 0.158 @ 2050 nm.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D1SC06026K

Reference58 articles.

1. Borates: A Rich Source for Optical Materials

2. Bulk characterization methods for non-centrosymmetric materials: second-harmonic generation, piezoelectricity, pyroelectricity, and ferroelectricity

3. Novel ultraviolet (UV) nonlinear optical (NLO) materials discovered by chemical substitution-oriented design