Chemoselective cycloadditions to epoxide derivatives of erucic acid with CO2 and CS2: controlled access to value-added bio-derived compounds

Author:

Álvarez-Miguel Lucía1ORCID,Mosquera Marta E. G.1ORCID,Whiteoak Christopher J.1ORCID

Affiliation:

1. Universidad de Alcalá, Grupo SOSCATCOM, Departamento de Química Orgánica y Química Inorgánica, Facultad de Farmacia and Instituto de Investigación Química Andrés M. del Río (IQAR), Campus Universitario, Ctra.Madrid-Barcelona Km. 33, 600, 28871 Alcalá de Henares, Madrid, Spain

Abstract

Highly selective methods for the synthesis of cyclic carbonate and dithiocarbonate derivatives of Erucic acid have been developed through synthesis of intermediate epoxides and catalytic couplings with CO2/CS2.

Funder

Ministerio de Ciencia e Innovación

Universidad de Alcalá

Comunidad de Madrid

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

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