Interaction of an imidazolium-2-amidinate (NHC-CDI) zwitterion with zinc dichloride in dichloromethane: role as ligands and C–Cl activation promoters-Reference-Cited by-同舟云学术

Interaction of an imidazolium-2-amidinate (NHC-CDI) zwitterion with zinc dichloride in dichloromethane: role as ligands and C–Cl activation promoters

Published:2018 Issue:89 Volume:54 Page:12586-12589
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Sánchez-Roa David¹²³⁴⁵,Santiago Tomás G.⁶⁷⁸⁵,Fernández-Millán Maria¹²³⁴⁵,Cuenca Tomás¹²³⁴⁵,Palma Pilar⁶⁷⁸⁵^ORCID,Cámpora Juan⁶⁷⁸⁵^ORCID,Mosquera Marta E. G.¹²³⁴⁵^ORCID

Affiliation:

1. Departamento de Química Orgánica y Química Inorgánica

2. Instituto de Investigacion en Química “Andres M. del Río” (IQAR) Universidad de Alcalá

3. Campus Universitario

4. Madrid

5. Spain

6. Instituto de Investigaciones Químicas

7. CSIC-Universidad de Sevilla

8. 41092 Sevilla

Abstract

Investigation of the interaction of a NHC-CDI zwitterion with ZnCl₂ in dichloromethane led to the serendipitous discovery of a highly selective, double C–Cl activation of dichloromethane.

Funder

Secretaría de Estado de Investigación, Desarrollo e Innovación

Universidad de Alcalá

European Regional Development Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CC/C8CC07661H

Reference21 articles.

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2. Zwitterionic amidinates as effective ligands for platinum nanoparticle hydrogenation catalysts

3. Copper(I) Complexes of Zwitterionic Imidazolium-2-Amidinates, a Promising Class of Electroneutral, Amidinate-Type Ligands

4. N-Heterocyclic Carbene–Carbodiimide (“NHC–CDI”) Adduct or Zwitterionic-Type Neutral Amidinate-Supported Magnesium(II) and Zinc(II) Complexes

5. Main-Chain Zwitterionic Supramolecular Polymers Derived from N-Heterocyclic Carbene–Carbodiimide (NHC–CDI) Adducts

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