Zwitterionic amidinates as effective ligands for platinum nanoparticle hydrogenation catalysts

Author:

Martínez-Prieto L. M.12345ORCID,Cano I.12345,Márquez A.6789,Baquero E. A.12345,Tricard S.12345,Cusinato L.12345,del Rosal I.12345,Poteau R.12345ORCID,Coppel Y.1011121314,Philippot K.1011121314ORCID,Chaudret B.12345,Cámpora J.6789,van Leeuwen P. W. N. M.12345ORCID

Affiliation:

1. LPCNO

2. Laboratoire de Physique et Chimie des Nano-Objets

3. UMR5215 INSA-CNRS-UPS

4. Institut des Sciences Appliquées

5. F-31077 Toulouse

6. Instituto de Investigaciones Químicas

7. CSIC-Universidad de Sevilla

8. 41092 Sevilla

9. Spain

10. CNRS

11. LCC (Laboratoire de Chimie de Coordination)

12. Université de Toulouse

13. UPS

14. INPT

Abstract

Pt NPs covered with zwitterionic amidinates as ligands exhibit an exciting ligand effect in the hydrogenation of carbonyl groups when electron donor/acceptor groups are introduced in theN-substituents.

Funder

Centre National de la Recherche Scientifique

Institut National des Sciences Appliquées Rouen

Ministerio de Economía y Competitividad

Consejo Superior de Investigaciones Científicas

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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3. Nanocatalysis Series Nanoscience and Technology, ed. H. Ulrich and L. Uzi, Springer, Heidelberg, 2007

4. Reduced Transition Metal Colloids:  A Novel Family of Reusable Catalysts?

5. Nanoparticles and Catalysis, Wiley-Interscience, New York, 2008

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