Insights into disilylation and distannation: sequence influence and ligand/steric effects on Pd-catalyzed difunctionalization of carbenes-Reference-Cited by-同舟云学术

Insights into disilylation and distannation: sequence influence and ligand/steric effects on Pd-catalyzed difunctionalization of carbenes

Published:2018 Issue:6 Volume:47 Page:1819-1826
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Yue Xiaoyu¹²³⁴,Shan Chunhui¹²³⁴,Qi Xiaotian¹²³⁴,Luo Xiaoling⁵⁶³⁴,Zhu Lei¹²³⁴,Zhang Tao¹²³⁴,Li Yuanyuan⁷⁸⁹⁴,Li Yingzi¹²³⁴,Bai Ruopeng¹²³⁴^ORCID,Lan Yu¹²³⁴^ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering

2. Chongqing University

3. Chongqing 400030

4. P. R. China

5. College of Chemistry

6. Chongqing Normal University

7. School of Biological and Chemical Engineering

8. Chongqing University of Education

9. Chongqing 400067

Abstract

Density functional theory (DFT) calculation has been used to reveal the mechanism of Pd-catalyzed disilylation of carbene, which is a pathway to construct disilylmethane derivatives.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/DT/C7DT04084A

Reference93 articles.

1. Silicon-based cross-coupling reaction: an environmentally benign version

2. Hypervalent Silicon as a Reactive Site in Selective Bond-Forming Processes

3. T. Hiyama , in Organometallics in Synthesis: Third Manual , ed. M. Schlosser , John Wiley & Sons , Hoboken, NJ , 2013 , p. 373