Diazo compounds and palladium–aryl complexes: trapping the elusive carbene migratory insertion organometallic products-Reference-Cited by-同舟云学术

Diazo compounds and palladium–aryl complexes: trapping the elusive carbene migratory insertion organometallic products

Published:2022 Issue:39 Volume:51 Page:14847-14851
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Villalba Francisco¹,Albéniz Ana C.¹^ORCID

Affiliation:

1. IU CINQUIMA/Química Inorgánica, Universidad de Valladolid, 47071 Valladolid, Spain

Abstract

Caught right after migratory insertion of a non-stabilized carbene into a Pd–Ar bond. The new allylic and benzylic palladium complexes model key intermediates in Pd-catalyzed coupling reactions of diazoalkanes.

Funder

Ministerio de Educación, Cultura y Deporte

Consejería de Educación, Junta de Castilla y León

Ministerio de Ciencia e Innovación

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT02775E

Reference49 articles.

1. Palladium-catalyzed insertion reactions of trimethylsilyldiazomethane

2. Palladium-catalyzed carbene insertion into benzyl bromides

3. Cross-Coupling Reactions Involving Metal Carbene: From C═C/C–C Bond Formation to C–H Bond Functionalization

4. Transition-Metal-Catalyzed Cross-Couplings through Carbene Migratory Insertion

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