A heterometallic macrocycle as a redox-controlled molecular hinge-Reference-Cited by-同舟云学术

A heterometallic macrocycle as a redox-controlled molecular hinge

Published:2015 Issue:5 Volume:44 Page:2252-2258
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Schouwey Clément¹²³⁴,Papmeyer Marcus¹²³⁴,Scopelliti Rosario¹²³⁴,Severin Kay¹²³⁴

Affiliation:

1. Institut des Sciences et Ingénierie Chimiques

2. Ecole Polytechnique Fédérale de Lausanne (EPFL)

3. 1015 Lausanne

4. Switzerland

Abstract

The geometry of a heterometallic Pt–Cu macrocycle is controlled by the redox state of the Cu centers. An elongated form with a long Pt⋯Pt distance is observed for Cu(i), whereas a folded form with a short Pt⋯Pt distance is found for Cu(ii).

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C4DT03331K

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