Lanthanide induced variability in localised CoII geometries of four triangular L3Co3IILnIII complexes-Reference-Cited by-同舟云学术

Lanthanide induced variability in localised Co^II geometries of four triangular L₃Co₃^IILn^III complexes

Published:2022 Issue:8 Volume:12 Page:4828-4835
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Dais Tyson N.¹^ORCID,Takano Rina²,Ishida Takayuki²^ORCID,Plieger Paul G.¹^ORCID

Affiliation:

1. School of Natural Sciences, Massey University, Private Bag 11 222, Palmerston North, New Zealand

2. Department of Engineering Science, Graduate School of Informatics and Engineering, The University of Electro-Communication, 1-5-1 Chofugaoka, Chofu, Tokyo 182-8585, Japan

Abstract

Four acyclic CoII–3LnIII triangle complexes are reported in which two Co ions in each complex are octahedral while the third Co exhibits a lanthanide dependent coordination geometry. Magnetic analysis of the La complex shows a large ZFS effect for Co.

Funder

Massey University

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/RA/D1RA08797E

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