“Sulfolefin”: a mixed sulfinamido-olefin ligand in enantioselective rhodium-catalyzed addition of arylboronic acids to trifluoromethyl ketones-Reference-Cited by-同舟云学术

“Sulfolefin”: a mixed sulfinamido-olefin ligand in enantioselective rhodium-catalyzed addition of arylboronic acids to trifluoromethyl ketones

Published:2014 Issue:8 Volume:12 Page:1211-1214
ISSN:1477-0520
Container-title:Org. Biomol. Chem.
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Valdivia Victoria¹²³⁴⁵,Fernández Inmaculada⁴⁵⁶⁷,Khiar Noureddine¹²³

Affiliation:

1. Instituto de Investigaciones Químicas

2. C.S.I.C-Universidad de Sevilla

3. 41092 Sevilla, Spain

4. Departamento de Química Orgánica y Farmacéutica

5. Facultad de Farmacia

6. Universidad de Sevilla

7. 41012 Sevilla, Spain

Abstract

Trifluoromethyl-substituted tertiary alcohols were obtained with good yields and enantioselectivities using the shelf stable sulfolefin-1 as a catalyst precursor.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/OB/C3OB41888J

Reference34 articles.

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3. Catalytic Enantioselective Addition of Allylic Organometallic Reagents to Aldehydes and Ketones

4. Asymmetric catalysis for the construction of quaternary carbon centres: nucleophilic addition on ketones and ketimines

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