Pd-catalyzed synthesis of 1-(hetero)aryl-2,2,2-trichloroethanols using chloral hydrate and (hetero)arylboroxines

Author:

Shimizu Minori1234,Okuda Yuta5264,Toyoda Koki7264,Akiyama Ryo5264,Shinozaki Hiraku7264,Yamamoto Tetsuya12345ORCID

Affiliation:

1. Department of Materials and Life Sciences

2. Tokyo Denki University

3. Adachi Tokyo 120-8551

4. Japan

5. Department of Materials Science and Engineering

6. Tokyo 120-8551

7. Department of Applied Chemistry

Abstract

N-heterocyclic carbene (NHC)-coordinated cyclometallated palladium complex (CYP) catalyzed (hetero)aryl addition of chloral hydrate using (hetero)arylboroxines, providing a new approach to 1-(hetero)aryl-2,2,2-trichloroethanols.

Funder

Tokyo Denki University

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

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