Radical chain mechanism for the S2O82−–S2O32−–Cu(<scp>ii</scp>) flow system explains high-amplitude pH oscillations in the NH4OH-modified version-Reference-Cited by-同舟云学术

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Radical chain mechanism for the S₂O₈²⁻–S₂O₃²⁻–Cu(ii) flow system explains high-amplitude pH oscillations in the NH₄OH-modified version

Published:2024 Issue:32 Volume:14 Page:22939-22946
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Kurin-Csörgei Krisztina¹^ORCID,Szalai István¹^ORCID,Orbán Miklós¹^ORCID

Affiliation:

1. Laboratory of Nonlinear Chemical Dynamics, Institute of Chemistry, Eötvös University, Pázmány Péter Sétány 1/A, Budapest 1117, Hungary

Abstract

Autocatalytic reaction of sulfate radical ions explains the oscillatory phenomena observed in flow reactors.

Funder

Nemzeti Kutatási Fejlesztési és Innovációs Hivatal

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/RA/D4RA02863E

Reference21 articles.

1. An all sulfur chemistry based oscillator

2. Systematic design of chemical oscillators. 48. Chemical oscillators in group VIA: the copper(II)-catalyzed reaction between thiosulfate and peroxodisulfate ions

3. Systematic design of chemical oscillators. 39. Chemical oscillators in group VIA: the copper(II)-catalyzed reaction between hydrogen peroxide and thiosulfate ion

4. Array programming with NumPy

5. I.Szalai , Peroxodisulfate–Thiosulfate–Cu(ii) Mechanism , 2024 , March 6, Retrieved from https://osf.io/7nxkg/

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