Stereodivergent, Diels–Alder-initiated organocascades employing α,β-unsaturated acylammonium salts: scope, mechanism, and application-Reference-Cited by-同舟云学术

Stereodivergent, Diels–Alder-initiated organocascades employing α,β-unsaturated acylammonium salts: scope, mechanism, and application

Published:2017 Issue:2 Volume:8 Page:1511-1524
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Abbasov Mikail E.¹²³⁴,Hudson Brandi M.⁵⁶⁷⁴^ORCID,Tantillo Dean J.⁵⁶⁷⁴,Romo Daniel¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry and Biochemistry

2. Baylor University

3. Waco

4. USA

5. Department of Chemistry

6. University of California-Davis

7. Davis

Abstract

Chiral α,β-unsaturated acylammonium salts are novel dienophiles enabling enantioselective Diels–Alder-lactonization (DAL) organocascades leading to cis- and trans-fused, bicyclic γ- and δ-lactones.

Funder

National Science Foundation

Welch Foundation

American Chemical Society Petroleum Research Fund

National Institutes of Health

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/SC/C6SC04273B

Reference88 articles.

1. Enantioselective Organocatalytic Diels-Alder Reactions

2. Synthesen in der hydroaromatischen Reihe

3. The Diels-Alder Reaction in Total Synthesis

4. New Strategies for Organic Catalysis: The First Highly Enantioselective Organocatalytic Diels−Alder Reaction

5. The First General Enantioselective Catalytic Diels−Alder Reaction with Simple α,β-Unsaturated Ketones

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