Catalytic protodeboronation of pinacol boronic esters: formal anti-Markovnikov hydromethylation of alkenes
Author:
Affiliation:
1. Organisch-Chemisches Institut
2. Westfälische Wilhelms-Universität
3. 48149 Münster
4. Germany
Abstract
Methane is formally added to alkenes via sequential hydroboration, Matteson-CH2-homologation and radical protodeboronation.
Funder
European Research Council
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/SC/C9SC02067E
Reference64 articles.
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2. Stereospecific functionalizations and transformations of secondary and tertiary boronic esters
3. A new stereospecific cross-coupling by the palladium-catalyzed reaction of 1-alkenylboranes with 1-alkenyl or 1-alkynyl halides
4. Palladium-Catalyzed Cross-Coupling Reactions of Organoboron Compounds
5. Cross-Coupling Reactions Of Organoboranes: An Easy Way To Construct CC Bonds (Nobel Lecture)
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