Borylative transition metal-free couplings of vinyl iodides with various nucleophiles, alkenes or alkynes-Reference-Cited by-同舟云学术

Borylative transition metal-free couplings of vinyl iodides with various nucleophiles, alkenes or alkynes

Published:2024 Issue:5 Volume:15 Page:1672-1678
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Seidler Gesa¹^ORCID,Schwenzer Max¹^ORCID,Clausen Florian¹,Daniliuc Constantin G.¹^ORCID,Studer Armido¹^ORCID

Affiliation:

1. Organisch-Chemisches Institut, Westfälische Wilhelms-Universität Münster, Corrensstraße 40, 48149 Munster, Germany

Abstract

The stereoselective synthesis of alkylboronic esters from vinyl iodides and various nucleophiles, alkenes or alkynes is presented. Reactions proceed through hydroborations and 1,2-metallate rearrangements without any transition metal catalyst.

Funder

Deutsche Forschungsgemeinschaft

Fonds der Chemischen Industrie

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D3SC06131K

Reference39 articles.

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4. Stereospecific functionalizations and transformations of secondary and tertiary boronic esters

5. Catalytic Asymmetric Hydroboration: Recent Advances and Applications in Carbon−Carbon Bond‐Forming Reactions

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