Catalytic Asymmetric Hydroboration: Recent Advances and Applications in Carbon−Carbon Bond‐Forming Reactions

Author:

Crudden Cathleen M.1,Edwards David1

Affiliation:

1. Queen’s University, Department of Chemistry, Kingston, Ontario, Canada K7 L 3N6

Publisher

Wiley

Subject

Organic Chemistry,Physical and Theoretical Chemistry

Reference123 articles.

1. Hydrogen Bonding to Active-Site Histidine in Peptidyl Boronic Acid Inhibitor Complexes of Chymotrypsin and Subtilisin:  Proton Magnetic Resonance Assignments and H/D Fractionation

2. Hydroborations catalysed by transition metal complexes

3. Transition metal catalyzed reactions of alkynes and boron hydrides: synthesis of 2-(cis-2-butenyl)pentaborane(9) and its conversion into monocarbon carboranes

4. Abbreviations: catecholborane (HBCat) = 1 3 2‐benzodioxaborole; pinacolborane (HBPin) = 4 4 5 5‐tetramethyl‐1 3 2‐dioxaborolane; TMDB = 4 4 6‐trimethyl‐1 3 2‐dioxaborinane; 9‐BBN = 9‐borabicyclo[3.3.1]nonane; BINAP = 2 2′‐bis(diphenylphosphanyl)‐1 1′‐binaphthyl; Bn = benzyl; COD = 1 5‐cyclooctadiene; Cp* = pentamethylcyclopentadienylide anion; Cy = cyclohexyl; DPPB = 1 4‐bis(diphenylphosphanyl)butane; NBD = norbornadiene; py = pyridine; TBS =tert‐butyldimethylsilyl.

5. Catalytic Hydroboration with Rhodium Complexes

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