Chemical reaction within a compact non-porous crystal containing molecular clusters without the loss of crystallinity

Author:

Zhang Ming12345,Yang Tao67851ORCID,Wang Zhenxing91085,Ma Xiong-Feng12345,Zhang Yuexing6785,Greer Samuel M.1112131415,Stoian Sebastian A.1112131415ORCID,Ouyang Zhong-Wen91085,Nojiri Hiroyuki16171819,Kurmoo Mohamedally2021222324,Zeng Ming-Hua67851ORCID

Affiliation:

1. Department of Chemistry and Pharmaceutical Sciences

2. Guangxi Normal University

3. Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources

4. Guilin

5. P. R. China

6. College of Chemistry and Chemical Engineering

7. Hubei University

8. Wuhan

9. Wuhan National High Magnetic Field Center & School of Physics

10. Huazhong University of Science and Technology

11. Department of Chemistry and Biochemistry

12. Florida State University

13. Tallahassee

14. USA

15. National High Magnetic Field Laboratory

16. Institute for Materials Research

17. Tohoku University

18. Sendai 980-8577

19. Japan

20. Institut de Chimie de Strasbourg

21. CNRS-UMR 7177

22. Université de Strasbourg

23. 67070 Strasbourg

24. France

Abstract

A yellow crystal with {FeII4O4} cubes is modified to a black crystal with {FeIII4O4} cubes via a SC–SC transformation.

Funder

National Science Foundation

Huazhong University of Science and Technology

Natural Science Foundation of Guangxi Province

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Reference61 articles.

1. G. Marin and G. S.Yablonsky, Kinetics of Chemical Reactions, Wiley-VCH, Weinheim, 2011

2. A. K. Cheetham and P.Day, Solid state chemistry techniques, Clarendon Press, Lincoln, United Kingdom, 1990

3. Coordination-Driven Self-Assembly Directs a Single-Crystal-to-Single-Crystal Transformation that Exhibits Photocontrolled Fluorescence

4. Three special issues for metal–organic framework reviews. Chem. Soc. Rev., 2009, 38, 12011508

5. Chem. Rev., 2012, 112, 6731268

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