Air oxidation-induced single-crystal-to-single-crystal transformation of mixed-valence tetranuclear Fe(<scp>ii</scp>)–Fe(<scp>iii</scp>) complexes-Reference-Cited by-同舟云学术

Air oxidation-induced single-crystal-to-single-crystal transformation of mixed-valence tetranuclear Fe(ii)–Fe(iii) complexes

Published:2022 Issue:38 Volume:51 Page:14429-14433
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Shin Jong Won¹,Ullah Ihsan¹,Tokunaga Ryuya²,Hayami Shinya²^ORCID,Min Kil Sik³^ORCID

Affiliation:

1. Department of Chemistry, Kyungpook National University, Daegu 41566, Republic of Korea

2. Department of Chemistry, Kumamoto University, Kumamoto 860-8555, Japan

3. Department of Chemistry Education, Kyungpook National University, Daegu 41566, Republic of Korea

Abstract

We synthesized a mixed-valence tetranuclear complex and observed air oxidation-induced single-crystal-to-single-crystal transformation of the complex through oxidation of Fe(ii) to Fe(iii), deprotonation, and ligand exchange.

Funder

National Research Foundation of Korea

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT02551E

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