Single and double activation of acetone by isolobal BN and BB triple bonds-Reference-Cited by-同舟云学术

Single and double activation of acetone by isolobal BN and BB triple bonds

Published:2018 Issue:24 Volume:9 Page:5354-5359
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Böhnke Julian¹²³⁴⁵,Brückner Tobias¹²³⁴⁵,Hermann Alexander¹²³⁴⁵,González-Belman Oscar F.⁶⁷⁸⁹,Arrowsmith Merle¹²³⁴⁵^ORCID,Jiménez-Halla J. Oscar C.⁶⁷⁸⁹^ORCID,Braunschweig Holger¹²³⁴⁵^ORCID

Affiliation:

1. Institut für Anorganische Chemie

2. Julius-Maximilians-Universität Würzburg

3. 97074 Würzburg

4. Germany

5. Institute for Sustainable Chemistry & Catalysis with Boron

6. Departamento de Química

7. Universidad de Guanajuato

8. 36050 Guanajuato

9. México

Abstract

Polar and apolar boron-based triple bonds promote the single and double C–H activation of acetone following similar coordination-deprotonation mechanisms.

Funder

H2020 European Research Council

Consejo Nacional de Ciencia y Tecnología

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/SC/C8SC01249K

Reference34 articles.

1. Bildung, Struktur und Reaktivität von (Pentafluorphenyl)bor‐tert‐butylimid und seinem Cyclodimeren

2. On the Directed Gas Phase Synthesis of the Imidoborane Molecule (HNBH) — An Isoelectronic Molecule of Acetylene (HCCH)