Hydrosilylation of BB triple bonds: catalyst- and reductant-free construction of B–Si bonds and B<sub>2</sub>Si heterocycles-Reference-Cited by-同舟云学术

Hydrosilylation of BB triple bonds: catalyst- and reductant-free construction of B–Si bonds and B₂Si heterocycles

Published:2024 Issue:24 Volume:60 Page:3259-3262
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Brückner Tobias¹²,Duwe Dario¹²^ORCID,Fantuzzi Felipe¹²³⁴^ORCID,Heß Merlin¹²,Dewhurst Rian D.¹²^ORCID,Radacki Krzysztof¹²^ORCID,Braunschweig Holger¹²^ORCID

Affiliation:

1. Institute for Inorganic Chemistry, Julius-Maximilians-Universität Würzburg, Am Hubland, Würzburg 97074, Germany

2. Institute for Sustainable Chemistry & Catalysis with Boron, Julius-Maximilians-Universität Würzburg, Am Hubland, Würzburg 97074, Germany

3. Institute for Physical and Theoretical Chemistry, Julius-Maximilians-Universität Würzburg, Emil-Fischer-Straße 42, Würzburg 97074, Germany

4. School of Chemistry and Forensic Science, University of Kent, Park Wood Rd, Canterbury CT2 7NH, UK

Abstract

Hydrosilanes undergo mild, uncatalyzed single and double 1,2-addition across the B–B triple bonds of diborynes, leading to an unsymmetrical silyldiborene and a compound with a novel three-membered B2Si ring.

Funder

Alexander von Humboldt-Stiftung

Deutsche Forschungsgemeinschaft

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior

H2020 European Research Council

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CC/D4CC00141A

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