Bilayered lanthanide squarate hydrates (Ln = Eu to Lu) and magnetization reversal barriers of 21 K for Ln = Tm and 57 K for Yb-Reference-Cited by-同舟云学术

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Bilayered lanthanide squarate hydrates (Ln = Eu to Lu) and magnetization reversal barriers of 21 K for Ln = Tm and 57 K for Yb

Published:2023 Issue:26 Volume:52 Page:8873-8882
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Takano Rina¹,Masuda Koki²,Cho Keigo²,Kitagawa Yasutaka²,Ishida Takayuki¹^ORCID

Affiliation:

1. Department of Engineering Science, Graduate School of Informatics and Engineering, The University of Electro-Communications, 1-5-1 Chofugaoka, Chofu, Tokyo 182-8585, Japan

2. Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka 560-8531, Japan

Abstract

A synthetic method for [Ln2(sq)3(H2O)8]n (Ln-sq; Ln = 63Eu-71Lu) was established. Compound Tm-sq can be regarded as a rare example in Tm SIMs, and the magnetization reversal barrier of Yb-sq is one of the largest in Yb SIMs known so far.

Funder

Ministry of Education, Culture, Sports, Science and Technology

Japan Society for the Promotion of Science

Murata Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D2DT03878A

Reference69 articles.

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2. Lanthanide Single-Molecule Magnets

3. Lanthanides in molecular magnetism: old tools in a new field

4. Magnetic hysteresis up to 80 kelvin in a dysprosium metallocene single-molecule magnet

5. Single-molecule magnets beyond a single lanthanide ion: the art of coupling

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