Combination of single-molecule magnet behaviour and luminescence properties in a new series of lanthanide complexes with tris(pyrazolyl)borate and oligo(β-diketonate) ligands

Author:

Mikhalyova Elena A.123ORCID,Zeller Matthias4567,Jasinski Jerry P.4897,Butcher Raymond J.10117ORCID,Carrella Luca M.12131415,Sedykh Alexander E.1216171518ORCID,Gavrilenko Konstantin S.1923202,Smola Sergey S.21223,Frasso Michael423247,Cazorla Sebastian Calderon4567,Perera Kuluni4567,Shi Anni4567,Ranjbar Habib G.4567,Smith Casey4567,Deac Alexandru4567,Liu Youlin4567,McGee Sean M.25262715,Dotsenko Vladimir P.21223,Kumke Michael U.25262715,Müller-Buschbaum Klaus1216171518ORCID,Rentschler Eva12131415ORCID,Addison Anthony W.428297ORCID,Pavlishchuk Vitaly V.123ORCID

Affiliation:

1. L. V. Pisarzhevskii Institute of Physical Chemistry of the National Academy of Sciences of the Ukraine

2. Kiev

3. Ukraine

4. Department of Chemistry

5. Purdue University

6. West Lafayette

7. USA

8. Keene State College

9. Keene

10. Chemistry Department Howard University

11. Washington

12. Institute of Inorganic and Analytical Chemistry

13. Johannes Gutenberg University Mainz

14. D-55128 Mainz

15. Germany

16. Justus-Liebig-Universität Giessen

17. 35392 Giessen

18. Institute of Inorganic Chemistry

19. Chembiocenter of Taras Shevchenko National University of Kiev

20. Enamine Ltd

21. A.V. Bogatsky Physico-Chemical Institute of the National Academy of Sciences of the Ukraine

22. 65080 Odessa

23. 217 Clark Hall West Virginia University

24. Morgantown

25. University of Potsdam

26. Institute of Chemistry

27. 14476 Potsdam

28. Drexel University

29. Philadelphia

Abstract

Mono-, di- & trinuclear ternary complexes of Dy3+ & Tb3+ with pyrazole & oligo-diketonates are both luminescent and single molecule magnets. Quantum yields & Ueff values decrease with higher nuclearity & reduced intramolecular Ln–Ln distance.

Funder

Volkswagen Foundation

Studienstiftung des Deutschen Volkes

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference102 articles.

1. Luminescent metal–organic frameworks

2. Luminescent multifunctional lanthanides-based metal–organic frameworks

3. Lanthanide luminescence for functional materials and bio-sciences

4. J.-C. G. Bünzli and S. V.Eliseeva , Photophysics of lanthanoid coordination compounds , in Comprehensive Inorganic Chemistry II , ed. V. W.-W. Yam , Elsevier B.V. , Amsterdam , 2013 , pp. 339–398

5. Lanthanides in molecular magnetism: so fascinating, so challenging

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