Synergetic catalysis of Se and Cu allowing diethoxylation of halomethylene ketones using O2 as the mild oxidant-Reference-Cited by-同舟云学术

Synergetic catalysis of Se and Cu allowing diethoxylation of halomethylene ketones using O2 as the mild oxidant

Published:2021 Issue:3 Volume:6 Page:454-458
ISSN:2058-9883
Container-title:Reaction Chemistry & Engineering
language:en
Short-container-title:React. Chem. Eng.

Author:

Cao Zhicheng¹²³⁴⁵,Deng Xin¹²³⁴,Chen Chao¹²³⁴,Liu Yonghong¹²³⁴,Yu Lei¹²³⁴^ORCID,Jiang Xuefeng⁵⁶⁷⁸⁴^ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering

2. Yangzhou University

3. Yangzhou

4. China

5. Shanghai Key Laboratory of Green Chemistry and Chemical Process

6. Department of Chemistry

7. East China Normal University

8. Shanghai 200062

Abstract

Catalyzed by PhSe(O)OH/Cu(OAc)₂, sp³-C–H alkylation of bromomethylene ketones produced useful α-carbonyl acetals under mild conditions. Bromo-containing substrates could release HBr during the reaction, avoiding the use of acidic additives.

Funder

Priority Academic Program Development of Jiangsu Higher Education Institutions

National Natural Science Foundation of China

Six Talent Peaks Project in Jiangsu Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Fluid Flow and Transfer Processes,Process Chemistry and Technology,Chemical Engineering (miscellaneous),Chemistry (miscellaneous),Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/RE/D0RE00471E

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