Metal-free difunctionalization of alkynes leading to alkenyl dithiocyanates and alkenyl diselenocyanates at room temperature

Author:

Lu Ling-Hui12345,Zhou Si-Jia12345,He Wei-Bao12345,Xia Wen6785,Chen Ping6785,Yu Xianyong6785,Xu Xinhua12345ORCID,He Wei-Min12345ORCID

Affiliation:

1. State Key Laboratory of Chemo/Biosensing and Chemometrics

2. Hunan University

3. Changsha

4. 410082

5. China

6. Key Laboratory of Theoretical Organic Chemistry and Functional Molecule of Ministry of Education

7. Hunan University of Science and Technology

8. Xiangtan 411201

Abstract

A facile and efficient protocol for the construction of alkenyl dithiocyanates and alkenyl diselenocyanates has been developed via stereoselective difunctionalization of alkynes with NaSCN or KSeCN at room temperature.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

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