En route to phosphonato iridium(i) complexes: the decisive effect of an intramolecular hydrogen bond
Author:
Affiliation:
1. Centro Universitario de la Defensa
2. ES-50090 Zaragoza
3. Spain
4. Departamento de Química Inorgánica
5. Instituto de Síntesis Química y Catálisis Homogénea (ISQCH)
6. Universidad de Zaragoza-CSIC
7. ES-50009 Zaragoza
Abstract
The decisive role of an intramolecular NH⋯OP hydrogen bond in the formation of a dimethyl phosphonato iridium(i) complex is shown.
Funder
Ministerio de Economía y Competitividad
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/DT/C5DT04038H
Reference40 articles.
1. Bifunctional Molecular Catalysis, in Topics in Organometallic Chemistry, ed. T. Ikariya and M. Shibasaki, Springer, Berlin Heidelberg, 2011, vol. 37
2. Metal–ligand bifunctional catalysis for asymmetric hydrogenation
3. Metal−Ligand Bifunctional Catalysis: A Nonclassical Mechanism for Asymmetric Hydrogen Transfer between Alcohols and Carbonyl Compounds
4. Exploiting Metal–Ligand Bifunctional Reactions in the Design of Iron Asymmetric Hydrogenation Catalysts
5. Cooperative Catalysis with First‐Row Late Transition Metals
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1. Reactivity of Ir(i)-aminophosphane platforms towards oxidants;Dalton Transactions;2023
2. Synthesis and reactivity of an iridium complex based on a tridentate aminophosphano ligand;Dalton Transactions;2022
3. Cyclometalated iridium complexes based on monodentate aminophosphanes;Dalton Transactions;2022
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