Cyclometalated iridium complexes based on monodentate aminophosphanes-Reference-Cited by-同舟云学术

Cyclometalated iridium complexes based on monodentate aminophosphanes

Published:2022 Issue:32 Volume:51 Page:12334-12351
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Palmese Marco¹^ORCID,Pérez-Torrente Jesús J.¹^ORCID,Passarelli Vincenzo¹^ORCID

Affiliation:

1. Departamento de Química Inorgánica, Instituto de Síntesis Química y Catálisis Homogénea (ISQCH), Universidad de Zaragoza-CSIC, C/Pedro Cerbuna 12, ES-50009 Zaragoza, Spain

Abstract

Ir(i)-aminophosphane complexes readily undergo reversible intramolecular C–H oxidative addition affording cyclometalated iridium(iii) derivatives. Formic acid dehydrogenation is catalysed by Ir-aminophosphane complexes.

Funder

Ministerio de Ciencia e Innovación

Gobierno de Aragón

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT02081E

Reference60 articles.

1. 783. Some aminophosphines

2. Notes. Some N-Substituted Aminodiphenylphosphines.

3. The Chloramination of Some Aminophosphines

4. En route to phosphonato iridium(i) complexes: the decisive effect of an intramolecular hydrogen bond

5. Amidophosphine-stabilized palladium complexes catalyse Suzuki-Miyaura cross-couplings in aqueous media

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