Selective modification of the metal coordination environment in heavy alkaline–earth iodide complexes

Author:

Fitts Lacey S.1234,Bierschenk Eric J.1234,Hanusa Timothy P.1234ORCID,Rheingold Arnold L.5674,Pink Maren819104,Young Victor G.819104

Affiliation:

1. Department of Chemistry

2. Vanderbilt University

3. Nashville

4. USA

5. Department of Chemistry and Biochemistry

6. University of California at San Diego

7. La Jolla

8. X-ray Crystallography Facility

9. University of Minnesota

10. Minneapolis

Abstract

The controlled formation of group 2 coordination complexes involves issues of metal acidity, ligand basicity, solvent effects, and steric pressure.

Funder

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Reference60 articles.

1. T. P. Hanusa , in Comprehensive Coordination Chemistry, ed. J. A. McCleverty and T. B. Meyer, Elsevier, Oxford, 2nd edn, 2004, vol. 3, pp. 1–92

2. T. P. Hanusa , E. J.Bierschenk, L. K.Engerer, K. A.Martin and N. R.Rightmire, in Comprehensive Inorganic Chemistry II, ed. J. Reedijk and K. Poeppelmeier, Elsevier, Amsterdam, 2nd edn, 2013, pp. 1133–1187

3. “Alkaline-Earth Metals in a Box”: Structures of Solvent-Separated Ion Pairs

4. Organic heterobimetallic complexes of the alkaline earth metals (Ae = Ca, Sr, Ba) with tetrahedral metallate anions of three-valent metals (M = B, Al, Ga, and V)

5. Probing the Salt‐Metathesis Route to Bis­(aryl)calcium Compounds: Structure of an Arylcalcate Complex

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