Effect of chalcogens on CO insertion into the palladium–methyl bond of [(N^N^X)Pd(CH3)]+ (X = O, S, Se) and on CO/ethylene copolymerisation-Reference-Cited by-同舟云学术

Effect of chalcogens on CO insertion into the palladium–methyl bond of [(N^N^X)Pd(CH3)]+ (X = O, S, Se) and on CO/ethylene copolymerisation

Published:2015 Issue:47 Volume:44 Page:20714-20727
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Kumar Kamlesh¹²³⁴,Darkwa James¹²³⁴

Affiliation:

1. Department of Chemistry

2. University of Johannesburg

3. Auckland Park 2006

4. South Africa

Abstract

Neutral and cationic palladium(ii) complexes of N_pz^N_py^X (X = O, S, and Se) tridentate ligands are used to study the CO insertion and CO/ethylene copolymerisation. This study sheds light on the use of chalcogens as hemilabile donor atoms.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT03929K

Reference59 articles.

1. Coordination−Insertion Copolymerization of Fundamental Polar Monomers

2. Late-Metal Catalysts for Ethylene Homo- and Copolymerization

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