Affiliation:
1. State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Renmin Street 5625, Changchun 130022, China
Abstract
The copolymers of carbon monoxide (CO) and olefins, namely polyketones, are a
family of widely used materials. In the catalytic preparation of these materials, palladium(II)
catalysts represent the most successful catalytic systems. The production of both alternating
and non-alternating polyketones has been achieved, with a great difference in their physical
properties. Herein, a variety of palladium(II) catalysts, employed for the copolymerization of
CO with various olefinic monomers, such as ethylene, α -olefins, styrene and polar vinyl
monomers, are fully summarized. The influence of important factors, such as solvents and
counterions on specific copolymerization, is also discussed. This review aims to enlighten the
design of new Pd catalysts with improved properties, as well as the development of new
polyketone materials.
Funder
Jilin Provincial Science and Technology Department Program
National Natural Science Foundation of China
Publisher
Bentham Science Publishers Ltd.
Cited by
11 articles.
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