Catalytic alkene skeletal modification for the construction of fluorinated tertiary stereocenters-Reference-Cited by-同舟云学术

Catalytic alkene skeletal modification for the construction of fluorinated tertiary stereocenters

Published:2022 Issue:15 Volume:13 Page:4327-4333
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Jiang Liyin¹^ORCID,Sarró Pau¹²^ORCID,Teo Wei Jie¹^ORCID,Llop Jordi³^ORCID,Suero Marcos G.¹^ORCID

Affiliation:

1. Institute of Chemical Research of Catalonia (ICIQ), Barcelona Institute of Science and Technology. Av. Països Catalans, 16, 43007 Tarragona, Spain

2. Departament de Química Analítica I Química Orgànica, Universitat Rovira I Virgili, C. Marcel·lí Domingo, 1, 43007 Tarragona, Spain

3. CIC BiomaGUNE, Basque Research and Technology Alliance, 20014 San Sebastián, Guipuzcoa, Spain

Abstract

We report a previously unknown disconnection approach to valuable fluorinated tertiary stereocenters based on the skeletal modification of 1,1-disubstituted alkenes by a Rh-catalyzed carbyne transfer.

Funder

H2020 European Research Council

Agencia Estatal de Investigacion

Marie Skłodowska-Curie Actions

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D2SC00968D

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