Triosmium alkylidyne clusters containing monophosphine and chiral diphosphine ligands. Crystal and molecular structures of [Os3(µ-H)2(CO)9(µ3-CPBunPh2)] and (R)-[Os3(µ-H)2(CO)8{µ3-CPPh2CH(Me)CH2PPh2}]
Author:
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/1995/DT/DT9950002831
Reference19 articles.
1. Some reactions of [Os3(µ-H)3(CO)9(µ3-CX)](X = OMe or Cl): the formation of C–N and C–P bonds
2. Synthesis of novel triosmium alkylidene carbonyl clusters. Crystal structures of [Os3(μ-H) 2(CO)9(μ3-CNC5H4-CHCH2)] and [Os3(μ-H)(CO)9(μ-C(H) NC5H4-η2-CHCH2)]
3. Reactions of the alkylidyne cluster [Os3(μ-H)2(CO)9(μ3-CNC5H4CHCH2)]. Crystal structures of [Os3(μ-H)2(CO)9(μ3-CNC5H4CHCH2)], [Os3(μ-H)2(CO)9(μ3-CNC5H4-μ-η2-CHCH)Os3(μ-H)(CO)10] and [Os3(μ-H)2(CO)9(μ-3-CNC5H4-C(O)CH3)]
4. H. J. Bestmann and R.Zimmermann, in Houben-Weyl: Methoden der Organischen Chemie, Bd. El, Georg Thieme, Stuttgart, 1982, p. 616.
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