Triplet dynamic nuclear polarization of pyruvate via supramolecular chemistry

Author:

Hamachi Tomoyuki1,Nishimura Koki1,Sakamoto Keita1,Kawashima Yusuke1,Kouno Hironori1,Sato Shunsuke2,Watanabe Go234ORCID,Tateishi Kenichiro56ORCID,Uesaka Tomohiro56,Yanai Nobuhiro178ORCID

Affiliation:

1. Department of Applied Chemistry, Graduate School of Engineering, Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka 819-0395, Japan

2. Department of Physics, School of Science, Kitasato University, Sagamihara, Kanagawa 252-0373, Japan

3. Kanagawa Institute of Industrial Science and Technology (KISTEC), 705-1 Shimoimaizumi, Ebina, Kanagawa 242-0435, Japan

4. Department of Data Science, School of Frontier Engineering, Kitasato University, Sagamihara, Kanagawa, 252-0373, Japan

5. Cluster for Pioneering Research, RIKEN, 2-1 Hirosawa, Wako, Saitama 351-0198, Japan

6. RIKEN Nishina Center for Accelerator-Based Science, 2-1 Hirosawa, Wako, Saitama 351-0198, Japan

7. Center for Molecular Systems (CMS), 744 Moto-oka, Nishi-ku, Fukuoka 819-0395, Japan

8. PRESTO, FOREST, JST, Honcho 4-1-8, Kawaguchi, Saitama 332-0012, Japan

Abstract

Formation of supramolecular complexes with cyclodextrins improves the dispersibility of pentacene derivatives in polar matrices, resulting in the first triplet dynamic nuclear polarization of an important bioprobe, pyruvate.

Funder

Shinnihon Foundation of Advanced Medical Treatment Research

Japan Society for the Promotion of Science

Precursory Research for Embryonic Science and Technology

Fusion Oriented REsearch for disruptive Science and Technology

Japan Science and Technology Agency

RIKEN

Kyushu University

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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