Frustrated Lewis pair-catalyzed double hydroarylation of alkynes with N-substituted pyrroles-Reference-Cited by-同舟云学术

Frustrated Lewis pair-catalyzed double hydroarylation of alkynes with N-substituted pyrroles

Published:2020 Issue:12 Volume:56 Page:1855-1858
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Guo Jing¹²³⁴^ORCID,Cheong Odelia⁵⁶⁷^ORCID,Bamford Karlee L.¹²³⁴^ORCID,Zhou Jiliang¹²³⁴^ORCID,Stephan Douglas W.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. University of Toronto

3. Toronto

4. Canada

5. Department of Chemistry and Biological Chemistry

6. Nanyang Technological University

7. Singapore

Abstract

Metal-free hydroarylation of alkynes with N-substituted pyrroles is shown to be efficiently mediated by B(C₆F₅)₃ to yield variants of dipyrrole methanes. The mechanism is shown to proceed via an FLP addition pathway.

Funder

Natural Sciences and Engineering Research Council of Canada

Canada Research Chairs

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CC/C9CC08654D

Reference31 articles.

1. Frustrated Lewis Pairs: From Concept to Catalysis

2. Frustrated Lewis Pairs

3. Frustrated Lewis Pair Chemistry: Development and Perspectives

4. Catalytic double hydroarylation of alkynes to 9,9-disubstituted 9,10-dihydroacridine derivatives by an electrophilic phenoxyphosphonium dication

5. The broadening reach of frustrated Lewis pair chemistry

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