Reactivity of rhodium and iridium peroxido complexes towards hydrogen in the presence of B(C6F5)3 or [H(OEt2)2][B{3,5-(CF3)2C6H3}4]
Author:
Affiliation:
1. Humboldt-Universität zu Berlin
2. Department of Chemistry
3. D-12489 Berlin
4. Germany
Abstract
Rh and Ir peroxido complexes have been studied in the metal-mediated hydrogenation of O2. Dissimilar reaction pathways have been found on using the Lewis-acid B(C6F5)3 or the Brønsted-acid [H(OEt2)2][B{3,5-(CF3)2C6H3}4] to give H2O·B(C6F5)3 or H2O2.
Funder
Deutsche Forschungsgemeinschaft
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT03853H
Reference110 articles.
1. Oxygen Reduction Reaction on Pt and Pt Bimetallic Surfaces: A Selective Review
2. Oxygen Tolerance of the H2-sensing [NiFe] Hydrogenase from Ralstonia eutropha H16 Is Based on Limited Access of Oxygen to the Active Site
3. Knall-gas Reaction-linked Fixation of Labelled Carbon Dioxide in an Autotrophic Streptomyces
4. Materials for fuel-cell technologies
5. FePt and CoPt Nanowires as Efficient Catalysts for the Oxygen Reduction Reaction
Cited by 5 articles. 订阅此论文施引文献 订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献
1. Autonomous execution of highly reactive chemical transformations in the Schlenkputer;Nature Chemical Engineering;2024-02-08
2. Rhodium disulfur and dioxygen complexes: examination of boron secondary coordination sphere effects;Journal of Coordination Chemistry;2022-04-28
3. Doping-induced decomposition of organic semiconductors: a caveat to the use of Lewis acid p-dopants;Journal of Materials Chemistry C;2022
4. Direct Synthesis of Hydrogen Peroxide in Water by Means of a Rh-Based Catalyst;Organometallics;2020-10-15
5. Rhodium(I) Complexes as Useful Tools for the Activation of Fluoroolefins;Synlett;2020-06-24
1.学者识别学者识别
2.学术分析学术分析
3.人才评估人才评估
"同舟云学术"是以全球学者为主线，采集、加工和组织学术论文而形成的新型学术文献查询和分析系统，可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容，当前同舟云学术共收录了国内外主流学术期刊6万余种，收集的期刊论文及会议论文总量共计约1.5亿篇，并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询！咨询电话：010-8811{复制后删除}0370
www.globalauthorid.com
TOP
Copyright © 2019-2024 北京同舟云网络信息技术有限公司 京公网安备11010802033243号 京ICP备18003416号-3