Reactivity of rhodium and iridium peroxido complexes towards hydrogen in the presence of B(C6F5)3 or [H(OEt2)2][B{3,5-(CF3)2C6H3}4]-Reference-Cited by-同舟云学术

Reactivity of rhodium and iridium peroxido complexes towards hydrogen in the presence of B(C6F5)3 or [H(OEt2)2][B{3,5-(CF3)2C6H3}4]

Published:2018 Issue:45 Volume:47 Page:16299-16304
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Baumgarth Hanna¹²³⁴,Meier Gregor¹²³⁴,von Hahmann Cortney N.¹²³⁴,Braun Thomas¹²³⁴^ORCID

Affiliation:

1. Humboldt-Universität zu Berlin

2. Department of Chemistry

3. D-12489 Berlin

4. Germany

Abstract

Rh and Ir peroxido complexes have been studied in the metal-mediated hydrogenation of O₂. Dissimilar reaction pathways have been found on using the Lewis-acid B(C₆F₅)₃ or the Brønsted-acid [H(OEt₂)₂][B{3,5-(CF₃)₂C₆H₃}₄] to give H₂O·B(C₆F₅)₃ or H₂O₂.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT03853H

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